There is no one best army list. There are too many variables to consider. This game is too much of a rock paper scissors game anyway, especially with Dark Eldar (paper)
There are a few unit choices, especially with allies and detachments however, that will usually give u a better chance of being successfull. Sticking with those units is your best bet. Then there are the units that would make it rather hard to win. Staying away from those will also help u win.
I may be the wrong person responding to this thread though because I don't play tournaments. Don't get me wrong, Im not saying there is anything wrong with a highly competative game, I just prefer causual games. I like winning as much as the next guy, just not enough to base my army list solely on the "highest chance if winning" In a tournament setting though, I guess that's the point