First of all, I love the idea and I think it will work. Couple of considerations tho:
1. The venoms will get shot down early ish as you will have to be aggressive to get the girls into his armour. That being the case, how about lose the extra SCs and spend points on something else? Same likely goes for night shields.
2. How about swap 2 venoms for two raiders? - just swap with the warriors, no need to buy new stuff. That way two venoms stay backfield laying down covering fire as the saying goes and you can have two slightly larger witch squads for multi-assault?
3. Consider succubus. Check mushkilla's batreps, he has had great success with them. I tried running two with witch squads yesterday and they were 'very angry birds' - sorry, just had to say that
back on topic, succubus kicks ass for the points and fits your theme well.
Finally, not sure about sybarite. Never got value from them myself.
Good luck, it's a great idea.