Here are a few threads that you might want to check out:
This thread, in the second post, has a really cheap and effective starting army. It shows you the basics for playing DE. From there you can build the list to suite your taste more after you figure out what exactly you want to do.
Plastikente's Dark Eldar Unit Guide is an indepth review of all our units in the codex, as well as popular builds for that unit. It is a excellent read for any new player.
The Pages of Pain is a thread compelation of different discussions on several topics. Always a good read to get a feel for other people's thoughts.
And finally The Big Batrep Thread can give you an idea of the playstyle of DE. There are wins and losses in there, and are a great read to see how others play the army, and see which playstyle you like better.
Also feel free to add to any of the pages with their own experiences as you start your army and start playing with them. Any questions, feel free to ask.
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Status:
Usurping Kabal leadership for his Patriarch
Current List:
First 2k GSC List