Somewhat surprised this hasn't been discussed yet:
Grey Knights can cast Sanctic powers, only suffering Perils on double 6s when everyone else would suffer Perils on any doubles. Similarly, Daemons can cast Malefic powers, only suffering Perils on double 6s when everyone else would suffer Perils on any doubles.
Our Helm of Spite causes psykers within 12" to suffer Perils on any double. How do these interact? Does the GK/Daemon ability take precedence, or does the Helm? Something for the FAQ?